Silica Sulfuric Acid/KClO3/Wet SiO2 as an Efficient Heterogeneous Method for the Oxidation of Alcohols under Mild Conditions.
ChemInform Vol. 35, No. 2
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DOI: 10.1002/chin.200402041دسترسی یکپارچه به مقالات، کتابها و ارائههای علمی استاد دکتر محمدعلی زلفیگل؛ گردآوریشده از منابع معتبر دانشگاهی
ChemInform Vol. 35, No. 2
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DOI: 10.1002/chin.200402041ChemInform Vol. 34, No. 52
Abstract For Abstract see ChemInform Abstract in Full Text.
DOI: 10.1002/chin.200352059Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 12, 2735–2743
Silica sulfuric acid in the presence of wet SiO2 was caused to react with oximes, hydrazones, semicarbazones, azines, and Schiff-bases. It was observed that it converts them to their corresponding carbonyl compounds in good to excellent yie…
DOI: 10.1080/714040985Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 12, 2667–2670
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition.
DOI: 10.1080/714040981ChemInform Vol. 34, No. 50
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DOI: 10.1002/chin.200350029ChemInform Vol. 34, No. 51
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DOI: 10.1002/chin.200351047Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 11, 2357–2361
A mild and efficient method for the synthesis of symmetrical ethers using silica sulfuric acid is reported. All reactions are performed under compeletly heterogeneous conditions in good to high yields.
DOI: 10.1080/714040949ChemInform Vol. 34, No. 47
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DOI: 10.1002/chin.200347119Tetrahedron Letters Vol. 44, No. 44, 8165–8167
DOI: 10.1016/j.tetlet.2003.09.036Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 10, 2107–2110
Alcohols were oxidized to their corresponding carbonyl compounds with KBrO 3 in the presence of silica chloride and wet SiO 2 , in solution and under solvent free conditions.
DOI: 10.1080/713744572ChemInform Vol. 34, No. 43
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DOI: 10.1002/chin.200343053Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 9, 2019–2025
Nitrophenols can be obtained via direct nitration of phenols with silica chloride, NaNO2, and wet SiO2 at room temperature in moderate to high yields.
DOI: 10.1080/10426500390228701Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 9, 1999–2002
A variety of alcohols underwent acetylation with acetic anhydride in the presence of silica chloride. All reactions were performed at room temperature and under completely heterogeneous conditions in good to high yields. We appreciate the f…
DOI: 10.1080/10426500390228684ChemInform Vol. 34, No. 37
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DOI: 10.1002/chin.200337053ChemInform Vol. 34, No. 36
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DOI: 10.1002/chin.200336046ChemInform Vol. 34, No. 35
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DOI: 10.1002/chin.200335078Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 8, 1709–1715
A combination of silica chloride and sodium nitrite in the presence of wet SiO 2 were used as an effective oxidizing agent for the oxidation of dihydropyridines to their corresponding pyridine derivatives under mild and heterogeneous condit…
DOI: 10.1080/10426500307836Russian Journal of Organic Chemistry Vol. 39, No. 8, 1191–1192
DOI: 10.1023/b:rujo.0000010193.00479.52Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 8, 1845–1849
A combination of silica sulfuric acid and sodium dichromate dihydrate in the presence of wet SiO 2 were used as an effective oxidizing agent for the oxidation of alcohols to their corresponding aldehyde or ketone derivatives in dichlorometh…
DOI: 10.1080/10426500307835ChemInform Vol. 34, No. 30
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DOI: 10.1002/chin.200330067ChemInform Vol. 34, No. 29
Neat chlorosulfonic acid reacted with silica gel to give silica sulfuric acid (I) in which sulfuric acid functions immobilized on the surface of silica gel via covalent bonding. Urazoles and bis-urazoles can be readily converted to their co…
DOI: 10.1002/chin.200329118ChemInform Vol. 34, No. 27
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DOI: 10.1002/chin.200327137Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 7, 1567–1570
Reaction of alcohols with hexamethyldisilazane in the presence of silica chloride provides efficiently the corresponding trimethylsilyl ethers. This system discriminates absolutely amines and thiols from alcohols.
DOI: 10.1080/10426500307866Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 7, 1617–1621
Alcohols are converted to esters in a mild, clean, and efficient reaction with acetic and formic acids in the presence of silica sulfuric acid. All reactions were performed under mild and completely heterogeneous conditions in refluxing n-h…
DOI: 10.1080/10426500307877