Journal2000
A Convenient Method for Production of Thionitrites and Disulfides Under Mild and Heterogeneous Condition
Synthetic Communications Vol. 30, No. 9, 1593–1597
چکیده
Thiols can be readily converted to their corresponding thionitrite with a combination of inorganic acidic salts and sodium nitrite in dichloromethane at room temperature. Disulfides result from the homolytic cleavage of the sulfur-nitrogen bond of the unstable thionitrite and subsequent coupling of the resultant thiyl radicals.
موضوعات و کلیدواژهها
Sulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsOrganic and Inorganic Chemical ReactionsChemistryDichloromethaneHomolysisSodium nitriteSulfurRadicalNitrogenBond cleavageNitriteCleavage (geology)Organic chemistryInorganic chemistryPhotochemistryCombinatorial chemistryCatalysisSolvent
ارجاع علمی
Mohammad Ali Zolfigol. “A Convenient Method for Production of Thionitrites and Disulfides Under Mild and Heterogeneous Condition.” Synthetic Communications, 2000. https://doi.org/10.1080/00397910008087194