Journal2016
A Convenient Method for the Preparation of 4,10-Dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.05,903,11]dodecane via Nitration of 1,4-Diformyl-2,3,5,6-tetrahydroxypiperazine Using [Msim]NO3
Synlett Vol. 27, No. 15, 2246–2250
چکیده
Improvement of methods for the synthesis of high-energetic scaffolds such as 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazaisowurtzitane or 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo [5.5.0.0 5,9 0 3,11 ]dodecane (TEX) is in demand because these materials may be used as high explosives. Herein, we demonstrate that the ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate ([Msim]NO 3 ) is an efficient reagent for the synthesis of TEX via nitration of 1,4-diformyl-2,3,5,6-tetrahydroxypiperazine (DFTHP) with high efficiency and short reaction time and under mild conditions.
موضوعات و کلیدواژهها
Energetic Materials and CombustionChemical Reactions and MechanismsChemistryNitrationDodecaneReagentIonic liquidNitric acidMedicinal chemistryOrganic chemistryCatalysis
ارجاع علمی
Mohammad Ali Zolfigol, Yadollah Bayat, Hossein Ghaderi, Mahmoud Zarei, Ehsan Noroozizadeh. “A Convenient Method for the Preparation of 4,10-Dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.05,903,11]dodecane via Nitration of 1,4-Diformyl-2,3,5,6-tetrahydroxypiperazine Using [Msim]NO3.” Synlett, 2016. https://doi.org/10.1055/s-0035-1562145