Journal2023دسترسی آزاد
A New Approach to the Ring-Opening of Epoxides under Mild and Green Conditions
Polycyclic aromatic compounds Vol. 44, No. 5, 3442–3455
چکیده
In this research work, we have designed and introduced [Zr-UiO-66-CO2H]Br as a versatile heterogeneous acid catalyst for the ring-opening of epoxides through SN1 and/or SN2 type mechanisms. In addition, the appropriate method for designing an active and efficient Bronsted acid site in metal-organic frameworks is discussed. [Zr-UiO-66-CO2H]Br was applied for the preparation of α-aryloxy alcohols by the condensation reaction of various epoxides with phenol or thiophenols under mild and green conditions.
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsMetal-Organic Frameworks: Synthesis and ApplicationsSulfur-Based Synthesis TechniquesChemistrySN2 reactionBrønsted–Lowry acid–base theoryRing (chemistry)CatalysisPhenolCondensationOrganic chemistryEpoxideCombinatorial chemistry
ارجاع علمی
Ali Reza Ataee-Najari, Mahmoud Zarei, Hossein Ahmadi, Mohammad Ali Zolfigol, Arash Ghorbani‐Choghamarani, Mojtaba Hosseinifard. “A New Approach to the Ring-Opening of Epoxides under Mild and Green Conditions.” Polycyclic aromatic compounds, 2023. https://doi.org/10.1080/10406638.2023.2235055