Journal2000
An Efficient Method for N-Nitrosation of Secondary Amines Under Mild and Heterogeneous Conditions
Synthetic Communications Vol. 30, No. 11, 2057–2060
چکیده
A combination of inorganic acidic salts or silica gel supported inorganic acids and sodium nitrite in the presence of wet SiO2 was used as an effective nitrosating agent for the nitrosation of secondary amines to their corresponding nitroso drivatives under mild and heterogeneous conditions in moderate to excellent yields. Mg(HSO4)2 and NaHSO4 are superior to all the aforementioned reagents in convenience, yield and purity of the isolated nitrosoamines.
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsCarbon dioxide utilization in catalysisSulfur-Based Synthesis TechniquesChemistryNitrosationReagentYield (engineering)Sodium nitriteNitrosoOrganic chemistryNitroso CompoundsReaction conditionsPrimary (astronomy)Combinatorial chemistryCatalysis
ارجاع علمی
Mohammad Ali Zolfigol, Ezat Ghaemi, Elaheh Madrakian, Maryam Kiany‐Borazjani. “An Efficient Method for N-Nitrosation of Secondary Amines Under Mild and Heterogeneous Conditions.” Synthetic Communications, 2000. https://doi.org/10.1080/00397910008087255