Journal2016

Application of {[4,4′-BPyH][C(CN)3]2} as a Bifunctional Nanostructured Molten Salt Catalyst for the Preparation of 2-Amino-4H-chromene Derivatives under Solvent-Free and Benign Conditions

Mohammad Ali Zolfigol, Meysam Yarie, Saeed Baghery

Synlett Vol. 27, No. 09, 1418–1422

چکیده

The bifunctional nanostructured molten salt [4,4′-bipyridine]-1,1′-diium tricyanomethanide has been employed as a highly efficient and powerful catalyst for the preparation of 2-amino-4 H -chromenes. A wide variety of aromatic aldehydes was condensed with malononitrile and resorcinol, 1-naphthol or 2-naphthol under mild and solvent-free conditions. This protocol has the advantages of short reaction times, high to excellent yields, and straightforward workup.

موضوعات و کلیدواژه‌ها

Multicomponent Synthesis of HeterocyclesSynthesis of Tetrazole DerivativesSynthesis and Characterization of Heterocyclic CompoundsChemistryBifunctionalMalononitrileMolten saltCatalysisSalt (chemistry)ResorcinolSolventOrganic chemistryGreen chemistryCombinatorial chemistryInorganic chemistryIonic liquid

ارجاع علمی

Mohammad Ali Zolfigol, Meysam Yarie, Saeed Baghery. “Application of {[4,4′-BPyH][C(CN)3]2} as a Bifunctional Nanostructured Molten Salt Catalyst for the Preparation of 2-Amino-4H-chromene Derivatives under Solvent-Free and Benign Conditions.” Synlett, 2016. https://doi.org/10.1055/s-0035-1561345