Journal2022دسترسی آزاد
Catalytic Application of a Novel Basic Alkane‐sulfonate Metal‐organic Frameworks in the Preparation of Pyrido[2,3‐ d ]pyrimidines via a Cooperative Vinylogous Anomeric‐based Oxidation
ChemistrySelect Vol. 7, No. 47
چکیده
Abstract In this paper, we have developed and introduced [Zr‐UiO‐66‐PDC‐(CH 2 ) 4 ‐SO 3 ] as a basic alkane‐sulfonate metal‐organic framework (MOF) catalyst. This catalyst was applied in the three‐component reaction for the preparation of (mono, bis, tris and tetrakis) pyrido[2,3‐ d ]pyrimidines by reaction of various 3‐oxo‐3‐phenylpropanenitrile, 6‐amino‐1,3‐dimethylpyrimidine‐2,4(1 H ,3 H )‐dione and widespread of aldehydes with good to excellent yields under solvent‐free at 110 °C. The last step of the reaction proceeded via a cooperative vinylogous anomeric‐based oxidation (CVABO) as one of the fundamental and basic stereoelectronic concepts.
موضوعات و کلیدواژهها
Metal-Organic Frameworks: Synthesis and ApplicationsMulticomponent Synthesis of HeterocyclesChemical Synthesis and ReactionsCatalysisChemistrySulfonateAlkaneAnomerSolventMetalOrganic chemistryCombinatorial chemistry
ارجاع علمی
Hossein Ahmadi, Mahmoud Zarei, Mohammad Ali Zolfigol. “Catalytic Application of a Novel Basic Alkane‐sulfonate Metal‐organic Frameworks in the Preparation of Pyrido[2,3‐ d ]pyrimidines via a Cooperative Vinylogous Anomeric‐based Oxidation.” ChemistrySelect, 2022. https://doi.org/10.1002/slct.202202155