Journal2003

Catalytic Friedel–Crafts Acylation of Alkoxy Benzenes by Ferric Hydrogensulfate

Peyman Salehi, Mohammad Mahdi Khodaei, Mohammad Ali Zolfigol, Shahpour Zeinoldini

Synthetic Communications Vol. 33, No. 8, 1367–1373

چکیده

Friedel–Crafts acylation of alkoxy benzenes is achieved efficiently by reaction with aliphatic acid anhydrides in the presence of catalytic amounts of ferric hydrogensulfate, Fe(HSO4)3, in nitromethane. Alkyl benzenes and aryl halides, as well as aromatic anhydrides, remain intact under these conditions.

موضوعات و کلیدواژه‌ها

Chemical Synthesis and ReactionsOrganic and Inorganic Chemical ReactionsSulfur-Based Synthesis TechniquesChemistryFriedel–Crafts reactionNitromethaneCatalysisAcylationFerricOrganic chemistryArylAlkoxy groupHalideAlkylMedicinal chemistry

ارجاع علمی

Peyman Salehi, Mohammad Mahdi Khodaei, Mohammad Ali Zolfigol, Shahpour Zeinoldini. “Catalytic Friedel–Crafts Acylation of Alkoxy Benzenes by Ferric Hydrogensulfate.” Synthetic Communications, 2003. https://doi.org/10.1081/scc-120018697