Journal2000
Chemoselective N-nitrosation of secondary amines under mild and heterogeneous conditions via in situ generation of NOCl
Journal of Chemical Research Vol. 2000, No. 9, 420–422
چکیده
A combination of inorganic chloride salts [e.g. WCl6, AlCl 3 and ZnCl 2 ] and sodium nitrite in the presence of wet SiO 2 were used as an effective nitrosating agent for the nitrosation of secondary amines to their corresponding nitroso derivatives under mild and heterogeneous conditions in moderate to excellent yields.
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsNanomaterials for catalytic reactionsAmmonia Synthesis and Nitrogen ReductionNitrosationChemistrySodium nitriteIn situNitrosoNitriteChlorideInorganic chemistryNuclear chemistryOrganic chemistry
ارجاع علمی
Mohammad Ali Zolfigol, Farhad Shirini, Arash Ghorbani Choghamarani, Abolfazl Taqian‐Nasab, Hassan Keypour, Sadegh Salehzadeh. “Chemoselective N-nitrosation of secondary amines under mild and heterogeneous conditions via in situ generation of NOCl.” Journal of Chemical Research, 2000. https://doi.org/10.3184/030823400103168119