Journal1998

Dinitrogen Tetraoxide Complexes of Iron(III) and Copper(II) as Efficient and Mild Reagents for Oxidation of Hydroxy Compounds

Nasser Iranpoor, Habib Firouzabadi, Mohammad Ali Zolfigol

Bulletin of the Chemical Society of Japan Vol. 71, No. 4, 905–908

چکیده

Abstract Fe(NO3)3·1.5N2O4 is a highly efficient reagent for the oxidation of various classes of hydroxy compounds in dichloromethane at room temperature, or in the absence of solvent. Cu(NO3)2·N2O4 oxidizes different hydroxy compounds in refluxing carbon tetrachloride and is a highly selective reagent for oxidation of primary benzylic alcohols in refluxing EtOAc.

موضوعات و کلیدواژه‌ها

Oxidative Organic Chemistry ReactionsChemical Synthesis and ReactionsFree Radicals and AntioxidantsChemistryReagentCopperInorganic chemistryNuclear chemistryOrganic chemistry

ارجاع علمی

Nasser Iranpoor, Habib Firouzabadi, Mohammad Ali Zolfigol. “Dinitrogen Tetraoxide Complexes of Iron(III) and Copper(II) as Efficient and Mild Reagents for Oxidation of Hydroxy Compounds.” Bulletin of the Chemical Society of Japan, 1998. https://doi.org/10.1246/bcsj.71.905