Journal1997
Dinitrogen Tetroxide Complexes of Iron and Copper Nitrates as New Reagents for Selective Mono- and Dinitration of Phenolic Compounds
Synthetic Communications Vol. 27, No. 19, 3301–3311
چکیده
Fe(NO3)3. 1.5 N2O4 and Cu(NO3)2. N2O4 are easily prepared reagents for the efficient and selective mono- or dinitration of phenolic compounds. In comparison with metal nitrates, these complexes resemble a synergetic effect on the rates and the yields of the reactions. High ratio of p-nitrophenol formation vs o-nitrophenol is also observed in the mononitration reactions.
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsSulfur-Based Synthesis TechniquesChemical Reaction MechanismsChemistryReagentNitrophenolCopperMetalOrganic chemistryInorganic chemistryNuclear chemistryCatalysis
ارجاع علمی
H. Firouzabadi, Nasser Iranpoor, Mohammad Ali Zolfigol. “Dinitrogen Tetroxide Complexes of Iron and Copper Nitrates as New Reagents for Selective Mono- and Dinitration of Phenolic Compounds.” Synthetic Communications, 1997. https://doi.org/10.1080/00397919708005630