Journal1998
Dinitrogen Tetroxide Complexes of Iron(III) and Copper(II) Nitrates as New Versatile Reagents for Organic Synthesis. Efficient and Selective Oxidation of Sulfides to their Corresponding Sulfoxides Under Mild Conditions.
Synthetic Communications Vol. 28, No. 2, 377–385
چکیده
Fe(NO3)3. 1.5 N2O4 and Cu(NO3)2.N2O4 are new, stable, and highly efficient reagents for the quantitative transformation of sulfides to sulfoxides in dichloromethane or in the absence of solvent at room temperature. Cu(NO3)2.N2O4 is highly selective for the oxidation of aryl sulfides.
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsSulfur-Based Synthesis TechniquesSynthesis and Catalytic ReactionsChemistryReagentDichloromethaneArylCopperSolventOrganic synthesisSulfoxideInorganic chemistryOrganic chemistryCombinatorial chemistryCatalysis
ارجاع علمی
Habibi Firouzabadi, Nasser Iranpoor, Mohammad Ali Zolfigol. “Dinitrogen Tetroxide Complexes of Iron(III) and Copper(II) Nitrates as New Versatile Reagents for Organic Synthesis. Efficient and Selective Oxidation of Sulfides to their Corresponding Sulfoxides Under Mild Conditions..” Synthetic Communications, 1998. https://doi.org/10.1080/00397919808005730