Journal2019دسترسی آزاد
H2O2 as a green and environmentally benign reagent for the oxidation of Sulfides in the presence of {[K.18-Crown-6]X3}n (X= Br, I) compared with some other organic tribromides
Eurasian Chemical Communications Vol. 2, No. 1, 44–50
چکیده
In the presence of {[K.18-Crown-6]X3}n (X= Br, I)-as interesting trihalide reagents, organic sulfides were oxidized to their corresponding sulfoxides using H2O2 as a green reagent. Via in situ generation of HOX, {[K.18-Crown-6]X3}n activates H2O2 and variously substituted sulfides were selectively transformed into the corresponding sulfoxides. We compared the obtained results of {[K.18-Crown-6]X3}n with some other organic tribromides. Unexpectedly, in most cases, the results were similar.
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsSulfur-Based Synthesis TechniquesVanadium and Halogenation ChemistryReagentCrown (dentistry)TrihalideChemistryOrganic synthesisOrganic chemistryInorganic chemistryMedicinal chemistryMaterials scienceCatalysis
ارجاع علمی
Mohsen Rasooli, Mohammad Ali Zolfigol, Mohammad Ali Moslemin, Razieh Mohebat, Gholamabbas Chehardoli. “H2O2 as a green and environmentally benign reagent for the oxidation of Sulfides in the presence of {[K.18-Crown-6]X3}n (X= Br, I) compared with some other organic tribromides.” Eurasian Chemical Communications, 2019. https://doi.org/10.33945/sami/ecc.2020.1.5