Journal2010دسترسی آزاد
HIO3/KI: A new combination reagent for iodination of aromatic amines and trimethylsilylation of alcohols and phenols through in situ generation of iodine under mild conditions
ARKIVOC Vol. 2009, No. 13, 200–210
چکیده
A combination of iodic acid and potassium iodide has been used for trimethylsilylation of alcohols and phenols in the presence of HMDS and iodination of aromatic amines.The reactions occur very rapidly to provide the products in good to high yields in dichloromethane at room temperature while the use of toxic and corrosive molecular iodine is avoided.
موضوعات و کلیدواژهها
Vanadium and Halogenation ChemistryChemical Synthesis and ReactionsChemistryIodineReagentHalogenationPhenolsIn situOrganic chemistry
ارجاع علمی
Mohammad Ali Zolfigol, Ardeshir Khazaei, Eskandar Kolvari, Nadiya Koukabi, Hamid Soltani, Maryam Behjunia, Vahid Khakyzadeh. “HIO3/KI: A new combination reagent for iodination of aromatic amines and trimethylsilylation of alcohols and phenols through in situ generation of iodine under mild conditions.” ARKIVOC, 2010. https://doi.org/10.3998/ark.5550190.0010.d18