Journal2010دسترسی آزاد

Molybdatophosphoric acid as an efficient catalyst for the catalytic and chemoselective oxidation of sulfides to sulfoxides using urea hydrogen peroxide as a commercially available oxidant

Alireza Hasaninejad, Mohammad Ali Zolfigol, Gholamabbas Chehardoli, Mohammad Mokhlesi

Journal of the Serbian Chemical Society Vol. 75, No. 3, 307–316

چکیده

An efficient procedure for the chemoselective oxidation of alkyl (aryl) sulfides to the corresponding sulfoxides using urea hydrogen peroxide (UHP) in the presence of a catalytic amount of molybdatophosphoric acid at room temperature is described. The advantages of described method are: generality, high yield and chemoselectivity, short reaction time, low cost and compliment with green chemistry protocols.

موضوعات و کلیدواژه‌ها

Chemical Synthesis and ReactionsSulfur-Based Synthesis TechniquesPolyoxometalates: Synthesis and ApplicationsHydrogen peroxideCatalysisChemistryUreaPeroxideOrganic chemistryCombinatorial chemistry

ارجاع علمی

Alireza Hasaninejad, Mohammad Ali Zolfigol, Gholamabbas Chehardoli, Mohammad Mokhlesi. “Molybdatophosphoric acid as an efficient catalyst for the catalytic and chemoselective oxidation of sulfides to sulfoxides using urea hydrogen peroxide as a commercially available oxidant.” Journal of the Serbian Chemical Society, 2010. https://doi.org/10.2298/jsc1000001h