Journal2006

Molybdatophosphoric Acid/NaNO2as an Efficient Procedure for the Chemoselective N-Nitrosation of Secondary Amines

Mohammad Ali Zolfigol, Khodabakhsh Niknam, Fariba Nazari

Journal of the Chinese Chemical Society Vol. 53, No. 3, 669–676

چکیده

A combination of molybdatophosphoric acid and sodium nitrite in the presence of wet SiO2 was used as an effective nitrosating agent for the nitrosation of secondary amines under mild and heterogeneous conditions in good to excellent yields. Also, the results of a computational study are investigated in the gas phase for geometry and properties of proposed structures.

موضوعات و کلیدواژه‌ها

Chemical Synthesis and ReactionsCarbon dioxide utilization in catalysisAmmonia Synthesis and Nitrogen ReductionChemistryNitrosationSodium nitriteNano-Gas phaseNitritePhase (matter)Organic chemistryCombinatorial chemistryChemical engineering

ارجاع علمی

Mohammad Ali Zolfigol, Khodabakhsh Niknam, Fariba Nazari. “Molybdatophosphoric Acid/NaNO2as an Efficient Procedure for the Chemoselective N-Nitrosation of Secondary Amines.” Journal of the Chinese Chemical Society, 2006. https://doi.org/10.1002/jccs.200600088