Journal2004
Novel, Mild and Chemoselective Dehydrogenation of 2-Imidazolines with Trichloroisocyanuric Acid
Synlett Vol. 2004, No. 15, 2803–2805
چکیده
A rapid, mild and high-yielding method for dehydrogenation of a variety of structurally diverse 2-imidazolines to imidazoles using trichloroisocyanuric acid (TCCA) in the presence of DBU is reported. Chemoselective oxidation of 2-imidazolines can be achieved in the presence of sulfide and alcohol. The mild conditions of this procedure and the absence of any transition metal make this reaction suitable for safe laboratory use.
موضوعات و کلیدواژهها
Synthesis and Catalytic ReactionsSynthesis of heterocyclic compoundsSynthesis and Reactions of Organic CompoundsTrichloroisocyanuric acidDehydrogenationChemistryOrganic chemistryChemoselectivityAlcoholCombinatorial chemistryCatalysis
ارجاع علمی
Iraj Mohammadpoor‐Baltork, Mohammad Ali Zolfigol, Mohammad Abdollahi‐Alibeik. “Novel, Mild and Chemoselective Dehydrogenation of 2-Imidazolines with Trichloroisocyanuric Acid.” Synlett, 2004. https://doi.org/10.1055/s-2004-835635