Journal2001
One-pot Nitration of Phenols under Mild and Heterogeneous Conditions
Journal of Chemical Research Vol. 2001, No. 4, 140–142
چکیده
Nitrophenols can be obtained via nitrosation–oxidation of phenols with Oxone®, NaNO 2 and wet SiO 2 at room temperature in moderate to high yields. In situ generation of HNO 2 and the radical cation mechanism via the nitrous acid catalysed (NAC) pathway or hydrogen abstraction involving NO 2 appear to be applicable to phenol nitration using these reagents.
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsOxidative Organic Chemistry ReactionsSulfur-Based Synthesis TechniquesNitrationPhenolsNitrosationPhenolChemistryNitrous acidReagentOrganic chemistry
ارجاع علمی
Mohammad Ali Zolfigol, Mojtaba Bagherzadeh, Elaheh Madrakian, Ezat Ghaemi, Abolfazl Taqian‐Nasab. “One-pot Nitration of Phenols under Mild and Heterogeneous Conditions.” Journal of Chemical Research, 2001. https://doi.org/10.3184/030823401103169450