Journal2008

PEG-N2O4: An Efficient Nitrating Agent for the Selective Mono- and Dinitration of Phenols Under Mild Conditions

Mohammad Ali Zolfigol, Elaheh Madrakian, Ezat Ghaemi, Khodabakhsh Niknam

Synthetic Communications Vol. 38, No. 19, 3366–3374

چکیده

N2O4 was easily impregnated on polyethyleneglycol to give a stable reagent. The polyethyleneglycol-N2O4 (PEG-N2O4) system was used as an effective nitrating agent for the nitration of phenols. Mono- and dinitrophenols can be obtained via direct nitration of phenols in the presence of PEG-N2O4 at room temperature in moderate to high yields.

موضوعات و کلیدواژه‌ها

Chemical Synthesis and ReactionsSulfur-Based Synthesis TechniquesSynthesis of Indole DerivativesNitrationChemistryPhenolsReagentPEG ratioOrganic chemistry

ارجاع علمی

Mohammad Ali Zolfigol, Elaheh Madrakian, Ezat Ghaemi, Khodabakhsh Niknam. “PEG-N2O4: An Efficient Nitrating Agent for the Selective Mono- and Dinitration of Phenols Under Mild Conditions.” Synthetic Communications, 2008. https://doi.org/10.1080/00397910802136706