Journal2008

PEG‐N2O4 System as an Efficient Reagent both for the Rapid Oxidation of Urazoles and 1,4‐Dihydropyridines under Nonaqueous Conditions

Mohammad Ali Zolfigol, Ezat Ghaemi, Elaheh Madrakian, Khodabakhsh Niknam

Journal of the Chinese Chemical Society Vol. 55, No. 3, 704–711

چکیده

Abstract N2O4 was easily impregnated on polyethyleneglycol to give a stable reagent. Polyethyleneglycol‐N2O4 (PEG‐N2O4) system was used as an effective oxidizing agent for the oxidation of urazoles and bis‐urazoles to their corresponding triazolinediones and also for the aromatization of 1,4‐dihydropyridines into the corresponding pyridine derivatives under mild conditions at room temperature with good to excellent yields.

موضوعات و کلیدواژه‌ها

Chemical Synthesis and ReactionsMulticomponent Synthesis of HeterocyclesSynthesis and Biological EvaluationChemistryReagentOxidizing agentAromatizationPEG ratioPyridinePEG 400Combinatorial chemistryInorganic chemistryNuclear chemistryMedicinal chemistryOrganic chemistryPolyethylene glycolCatalysis

ارجاع علمی

Mohammad Ali Zolfigol, Ezat Ghaemi, Elaheh Madrakian, Khodabakhsh Niknam. “PEG‐N2O4 System as an Efficient Reagent both for the Rapid Oxidation of Urazoles and 1,4‐Dihydropyridines under Nonaqueous Conditions.” Journal of the Chinese Chemical Society, 2008. https://doi.org/10.1002/jccs.200800106