Journal2005
Silica chromate as an oxidising agent for the chemoselective oxidation of alcohols and the oxidative deprotection of trimethylsilyl ethers
Mendeleev Communications Vol. 15, No. 3, 113–116
چکیده
Silica chromate easily converts primary and secondary alcohols to corresponding carbonyl compounds in the presence of wet SiO2 both in dichloromethane and under solvent-free conditions at room temperature with good to excellent yields. Primary and secondary trimethylsilyl ethers were converted into the corresponding carbonyl compounds or alcohols by using silica chromate and wet SiO2 in dichloromethane at room temperature with good to excellent yields
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsOxidative Organic Chemistry ReactionsMulticomponent Synthesis of HeterocyclesChemistryDichloromethaneTrimethylsilylChromate conversion coatingOrganic chemistryPrimary (astronomy)Alcohol oxidationSolventOxidizing agentAcetonitrileSilica gelAlcoholCorrosion
ارجاع علمی
Mohammad Ali Zolfigol, Farhad Shirini, Iraj Mohammadpoor‐Baltork, Arash Gh. Choghamarani, Maryam Hajjami, Abdol M. Sedaghat. “Silica chromate as an oxidising agent for the chemoselective oxidation of alcohols and the oxidative deprotection of trimethylsilyl ethers.” Mendeleev Communications, 2005. https://doi.org/10.1070/mc2005v015n03abeh002005