Journal2008
Silica Sulfuric Acid and Al(HSO4)3: As Efficient Catalysts for the Formylation of Alcohols by Using Ethyl Formate under Heterogeneous Conditions
Journal of the Chinese Chemical Society Vol. 55, No. 4, 885–889
چکیده
Abstract A mixture of ethyl formate and a catalytic amount of silica sulfuric acid or Al(HSO4)3 as suitable formylating systems can formylate various alcohols to their corresponding formate ester derivatives under mild, nearly neutral and heterogeneous conditions at room temperature with good to excellent yields.
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsChemical Synthesis and AnalysisCarbon dioxide utilization in catalysisChemistryEthyl formateFormylationCatalysisSulfuric acidFormateAlcoholOrganic chemistryMethyl formateHeterogeneous catalysis
ارجاع علمی
Mohammad Ali Zolfigol, Gholamabbas Chehardoli, Mina Dehghanian, Khodabakhsh Niknam, Farhad Shirini, Ahmad Khoramabadi‐zad. “Silica Sulfuric Acid and Al(HSO4)3: As Efficient Catalysts for the Formylation of Alcohols by Using Ethyl Formate under Heterogeneous Conditions.” Journal of the Chinese Chemical Society, 2008. https://doi.org/10.1002/jccs.200800132