Journal2003

Silica Sulfuric Acid/NaNO 2 as a Novel Heterogeneous System for the Chemoselective α-Nitrosation of β-Diketones Under Mild Conditions

Mohammad Ali Zolfigol, Arash Ghorbani Choghamarani

Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 7, 1623–1629

چکیده

A combination of silica sulfuric acid and sodium nitrite in the presence of wet SiO 2 was used as an effective nitrosating agent for the nitrosation of g -diketones to their corresponding f -nitroso or f -oximinoketones under mild and heterogenous conditions in moderate to excellent yields.

موضوعات و کلیدواژه‌ها

Chemical Synthesis and ReactionsSulfur-Based Synthesis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsSulfuric acidNitrosationSodium nitriteChemistryNitrosoNitriteNano-Inorganic chemistryNuclear chemistryOrganic chemistryMaterials science

ارجاع علمی

Mohammad Ali Zolfigol, Arash Ghorbani Choghamarani. “Silica Sulfuric Acid/NaNO 2 as a Novel Heterogeneous System for the Chemoselective α-Nitrosation of β-Diketones Under Mild Conditions.” Phosphorus, sulfur, and silicon and the related elements, 2003. https://doi.org/10.1080/10426500307868