Journal2007

Silica Triflate as an Efficient Reagent for the Chemoselective Formylation of Alcohols

Farhad Shirini, Katayoun Marjani, Hossein Taherpour Nahzomi, Mohammad Ali Zolfigol

Phosphorus, sulfur, and silicon and the related elements Vol. 182, No. 6, 1245–1251

چکیده

Silica triflate, as a new and stable silica-based reagent, is prepared by a reaction of silica gel with trifluoromethane sulfonyl chloride at room temperature. This reagent can be used for the efficient and selective formylation of alcohols in the presence of phenols in a relatively short reaction time and high yields under heterogeneous reaction conditions.

موضوعات و کلیدواژه‌ها

Chemical Synthesis and ReactionsSulfur-Based Synthesis TechniquesChemical Synthesis and AnalysisReagentFormylationTrifluoromethanesulfonateSulfonylChemistryChlorideOrganic chemistrySilica gelPhenolsCatalysis

ارجاع علمی

Farhad Shirini, Katayoun Marjani, Hossein Taherpour Nahzomi, Mohammad Ali Zolfigol. “Silica Triflate as an Efficient Reagent for the Chemoselective Formylation of Alcohols.” Phosphorus, sulfur, and silicon and the related elements, 2007. https://doi.org/10.1080/10426500601160710