Journal2018
Synthesis of Nitroolefins and Nitroarenes under Mild Conditions
The Journal of Organic Chemistry Vol. 83, No. 7, 3645–3650
چکیده
1,3-Disulfonic acid imidazolium nitrate {[Dsim]NO 3 } was prepared and characterized as a new ionic liquid and nitrating agent for the ipso-nitration of various arylboronic acids and nitro-Hunsdiecker reaction of different α,β-unsaturated acids and benzoic acid derivatives, by in situ generation of NO 2 to give various nitroarenes and nitroolefins without using any cocatalysts and solvents under mild conditions.
موضوعات و کلیدواژهها
Ionic liquids properties and applicationsChemical Synthesis and ReactionsN-Heterocyclic Carbenes in Organic and Inorganic Chemistrynitroalkenesnitroaromatic compoundsionic liquidsipso-nitrationarylboronic acidsαβ-unsaturated acidsbenzoic acid derivativessolvent-free synthesis
ارجاع علمی
Mahmoud Zarei, Ehsan Noroozizadeh, Ahmad Reza Moosavi‐Zare, Mohammad Ali Zolfigol. “Synthesis of Nitroolefins and Nitroarenes under Mild Conditions.” The Journal of Organic Chemistry, 2018. https://doi.org/10.1021/acs.joc.7b03289