Journal2022دسترسی آزاد
Synthesis of novel triiodide ionic liquid based on quaternary ammonium cation and its use as a solvent reagent under mild and solvent-free conditions
Heterocyclic Communications Vol. 28, No. 1, 58–66
چکیده
Abstract In this article, for the first time, N,N,N -triethyl-3-iodopropan-1-aminium triiodide [N 2223I ] [I 3 ] was synthesized and utilized as both a reagent and a solvent in combination with H 2 O 2 (35%) to convert aromatic compounds into their corresponding iodo derivatives. The iodination was accomplished in the absence of organic solvents, and in most instances, water was the sole extraction solvent used. The consumed reagent N,N,N -triethyl-3-iodopropan-1-aminium iodide was comfortably recycled.
موضوعات و کلیدواژهها
Chemical Synthesis and ReactionsVanadium and Halogenation ChemistryIonic liquids properties and applicationsChemistryReagentTriiodideSolventIonic liquidIodideAmmoniumOrganic chemistryHalogenationAmmonium iodideInorganic chemistryCatalysis
ارجاع علمی
Mahnaz Sakhdari, Nadiya Koukabi, Mohammad Ali Zolfigol. “Synthesis of novel triiodide ionic liquid based on quaternary ammonium cation and its use as a solvent reagent under mild and solvent-free conditions.” Heterocyclic Communications, 2022. https://doi.org/10.1515/hc-2022-0006