Journal2008

Trimethylsilylation of Hydroxyl Group with 1,1,1,3,3,3‐Hexamethyldisilazane (HMDS) Catalyzed by Tribromomelamine (TBM)

Arash Ghorbani‐Choghamarani, Mohammad Ali Zolfigol, Maryam Hajjami, Shila Jafari

Journal of the Chinese Chemical Society Vol. 55, No. 6, 1208–1213

چکیده

Abstract Tribromomelamine (TBM) can be used as a novel catalyst for the trimethylsilylation of alcohols and phenols with 1,1,1,3,3,3‐hexamethyldisilazane (HMDS). A wide variety of hydroxyl groups were selectively protected in CH2Cl2/CH3CN under mild conditions.

موضوعات و کلیدواژه‌ها

Chemical Synthesis and ReactionsSulfur-Based Synthesis TechniquesCarbon dioxide utilization in catalysisChemistryPhenolsCatalysisGroup (periodic table)Organic chemistryMedicinal chemistry

ارجاع علمی

Arash Ghorbani‐Choghamarani, Mohammad Ali Zolfigol, Maryam Hajjami, Shila Jafari. “Trimethylsilylation of Hydroxyl Group with 1,1,1,3,3,3‐Hexamethyldisilazane (HMDS) Catalyzed by Tribromomelamine (TBM).” Journal of the Chinese Chemical Society, 2008. https://doi.org/10.1002/jccs.200800180