Silica Chloride/NaNO 2 as a Novel Heterogeneous System for Production of Thionitrites and Disulfides Under Mild Conditions
Phosphorus, sulfur, and silicon and the related elements Vol. 178, No. 7, 1477–1481
Thiols can be readily converted to their corresponding thionitrites with a combination of silica chloride ( I ), wet SiO 2 and sodium nitrite in dichloromethane at room temperature. Disulfides result from the homolytic cleavage of the sulfu…
DOI: 10.1080/10426500307872